Chemistry Review Assignment #1
Due Tuesday, January 25
Kotz & Treichel
Chapter 7: 23,
27, 31, 33, 71
Additional Problems
1) Calculate the wavelength of a photon of visible light with a frequency of 0.66 × 1015sec-1. What is the energy of the photon? What is the wave number? (from DeKock & Gray: Problem 1-5)
2) For each of the following sources of radiation, calculate the total energy density and estimate (hint: graphically) the fraction of energy in the visible range (400-700 nm). Assume each acts as a blackbody radiator.
a: glowing coals
in a fireplace (T = 1000 K)
b: filament
of an incandescent bulb (T = 2500 K)
c: surface of
the sun (T = 6000 K)
3) To remove an electron from the interior of platinum, 5 eV are required.
a: What is the minimum frequency of light required to observe the photoelectric effect with platinum?b: If l = 200 nm, what will be the velocity of the emitted photon?
Note: 1 eV = 8,065 cm-1; 1 eV = 1.60 × 10-12 erg; 1 erg = 10-7 J