Quiz #5
General chemistry August 7, 2002

1.     A. HI because it is larger
        B. CH3COOH because there are more oxygens to distribute the charge
        C. HClO4 because there are more oxygens to distribute the charge
2.     pH = -log[H+]
        [H+] = 10-8.2 = 6.3 x 10-9 M
        basic
3.     pOH = 14 - pH = 14 - 8.2 = 5.8
        pOH = -log[-OH]
        [-OH] = 10-5.8 = 1.6 x 10-6 M
4.             HCNO ---->  H+   + -CNO
      start    1.0                0        0
    change   - x                + x    + x
equilibrium 1.0 -x            x        x

        K = [H+][-CNO]  = x2/1.0-x ~ x2/1.0 = 2.2 x 10-4
                [HCNO]

        x = 0.0148 M = [H+]
        pH = -log[H+] = 1.8

5. A. 0.0762 L x 0.1 moles/L = 0.00762 moles
        0.00762 moles/0.05 L = 0.152 M
    B. 7